Tag "chemistry"

Europium is a rare-earth metal responsible for the pure red glow in displays and other luminescent materials. For a long time, however, it refused to emit light when surrounded by certain organic molecules known as acylpyrazolone ligands. Chemists have now uncovered the reason: in europium complexes with these ligands, a 'black window' appears—a charge-transfer state in which the energy absorbed by the ligand is dissipated as heat rather than emitted as light. Understanding this mechanism opens the way to designing more efficient red-emitting materials for displays, fluorescent thermometers, and chemical sensors. The results have been published in Dalton Transactions.

Chemists from HSE University have discovered a way to carry out a reductive addition reaction without using an external reducing agent. Instead, the required 'resource' is supplied by the aldehyde itself, one of the reaction participants. This approach helps prevent unwanted side reactions, reduces toxicity, and simplifies the production and synthesis of organic molecules, including those used in the manufacture of medicines. The study has been published in Journal of Catalysis.

An international team including researchers from HSE MIEM has developed a catalyst that enables fast and low-cost hydrogen production from water. To achieve this, the scientists synthesised nanoparticles of a complex oxide containing six metals and anchored them onto various substrates. The catalyst supported on reduced graphene layers proved to be nearly three times more efficient than the same oxide without a substrate. This development could significantly reduce the cost of hydrogen production and accelerate the transition to green energy. The study has been published in ACS Applied Energy Materials. The work was carried out under a grant from the Russian Science Foundation.

An international team of researchers, including chemists from HSE University and the A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences (INEOS RAS), has developed a new method for synthesising aniline derivatives—compounds widely used in the production of medicines, dyes, and electronic materials. Instead of relying on toxic and expensive reagents, they proposed using tetrahydrofuran, which can be derived from renewable raw materials. The reaction was carried out in the presence of readily available cobalt salts and syngas. This approach reduces hazardous waste and simplifies the production process, making it more environmentally friendly. The study has been published in ChemSusChem.

Researchers at HSE University and the Institute of Petrochemical Synthesis of the Russian Academy of Sciences have discovered a way to control both the colour and brightness of the glow emitted by rare earth elements. Their luminescence is generally predictable—for example, cerium typically emits light in the ultraviolet range. However, the scientists have demonstrated that this can be altered. They created a chemical environment in which a cerium ion began to emit a yellow glow. The findings could contribute to the development of new light sources, displays, and lasers. The study has been published in Optical Materials.

A team of Russian researchers has synthesised a novel compound for boron neutron capture therapy (BNCT), a treatment for advanced cancer that uses the boron-10 isotope. The compound exhibits low toxicity, excellent water solubility, and eliminates the need for administering large volumes. Most importantly, the active substance reaches the tumour with minimal impact on healthy tissues. The study was published in the International Journal of Molecular Sciences shortly before World Cancer Day, observed annually on February 4.